The Metallocene Battery: Ultrafast Electron Transfer Self Exchange Rate Accompanied by a Harmonic Height Breathing
نویسندگان
چکیده
منابع مشابه
Ultrafast electron transfer, recombination and spin dynamics
The quenching of excited singlet methylene blue (IMB + * ) by N,N-dimethylaminomethylferrocene (FcN) in acetonitrile at room temperature has been studied using femtosecond pump-probe absorption spectroscopy. At high FcN concentration static quenching via an intermolecular electron transfer mechanism constitutes the predominating decay channel for l MB + * The time constants of the large amplitu...
متن کاملElectron self-exchange in azurin: calculation of the superexchange electron tunneling rate.
Electronic coupling between the copper atoms in an azurin dimer has been calculated in this conformationally well-defined system by using many-electronic wave functions. When one of the two water molecules forming intermolecular hydrogen bonds between the copper-ligating His-117 of the two azurins is removed, the calculated coupling element is reduced from 2.5 x 10(-6) to 1.1 x 10(-7) eV (1 eV ...
متن کاملUltrafast IR spectroscopy of photo-induced electron transfer in self-assembled donor-acceptor coordination cages.
Photo-induced processes in self-assembled coordination cages were studied by femtosecond infrared pump-probe spectroscopy. Densely packed, interpenetrated double cages were constructed from eight bis-monodentate redoxactive ligands bound to four Pd(ii) nodes. Two types of ligands consisting of electron rich phenothiazine (PTZ) or electron deficient anthraquinone (ANQ) chromophores were used to ...
متن کاملUltrafast single-electron transfer in coupled quantum dots driven by a few-cycle chirped pulse
Articles you may be interested in The influence of quantum dot size on the sub-bandgap intraband photocurrent in intermediate band solar cells Appl. Mixed state effects in waveguide electro-absorbers based on quantum dots Appl. Inhibited single-electron transfer by electronic band gap of two-dimensional Au quantum dot superlattice Appl. Final-state readout of exciton qubits by observing resonan...
متن کاملDirect simulation of electron transfer in the cobalt hexammine(ii/iii) self-exchange reaction.
We present an atomistic simulation of the cobalt hexammine(ii/iii) self-exchange reaction using path integral (PI) methods. We construct a simple force field for the system in its reactant state that includes parameters for both atom-atom interactions, and interactions with an explicit transferring electron represented in the PI framework. We then calculate the outer sphere free energy barrier ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Angewandte Chemie International Edition
سال: 2021
ISSN: 1433-7851,1521-3773
DOI: 10.1002/anie.202100174